Document size, selected paper and loaded paper must agree before a percentage scale has a physical meaning.
A printer's hardware margins can trigger a second fit-to-page operation outside the browser dialog.
Measure a known 50 or 100 mm feature; a visual page preview cannot prove physical scale.
The full explanation
A page can be laid out in real millimetres and still print at the wrong size, because the browser, the print dialog and the printer each get a chance to scale it. Getting graph paper or a calendar to come out at true size is mostly about knowing which settings to defeat. Read the complete guide for the reasoning, examples and definitions behind this answer.